Convergent synthesis and optical properties of near-infrared emitting bioluminescent infra-luciferins† †Electronic supplementary information (ESI) available: General experimental details, copies of 1H and 13C NMR spectra and optical imaging details. See DOI: 10.1039/c6ra19541e Click here for additional data file.

Gold(iii)–arene complexes by insertion of olefins into gold–aryl bonds† †Electronic supplementary information (ESI) available: Experimental details (syntheses, analytical data and copies of 1H, 13C and 31P NMR spectra), crystallographic data of 2 and computational details. CCDC 1526613 and 1538015. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00145b Click here for additional data file. Click here for additional data file.

Synthesis of a novel polycyclic ring scaffold with antimitotic properties via a selective domino Heck–Suzuki reaction† †Electronic supplementary information (ESI) available: Full experimental details, 1H and 13C NMR spectra and X-ray crystallographic data for compound 4d. CCDC 936207. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4sc02547d Click here for additional data file. Click here for additional data file.

Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile† †Electronic supplementary information (ESI) available: Experimental details including characterization data, copies of 1H, 13C NMR and NOESY spectra. See DOI: 10.1039/c5sc04066c Click here for additional data file.

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Exceptional time response, stability and selectivity in doubly-activated phenyl selenium-based glutathione-selective platform† †Electronic supplementary information (ESI) available: 1H, 13C, 77Se and 2D NMR, HRMS spectra of compounds, details of the synthetic procedure, additional fluorescent spectra, confocal microscopy image, DFT calculation data, live imaging movie. See DOI: 10.1039/c5sc02090e Click here for additional data file. Click here for additional data file.

Versatile synthesis and enlargement of functionalized distorted heptagon-containing nanographenes† †Electronic supplementary information (ESI) available: General details, synthesis and spectroscopy data of new compounds and copies of 1H and 13C-NMR spectra of new compounds. Experimental details on optical and electrochemical measurements. Crystal data and structure refinement of compounds 2, 6a, 6d and 6h. Further details on theoretical calculations and Cartesian coordinates of computed structures. VT-1H-NMR, 2D-NMR and HRMS spectra of compounds 1 and 2. CCDC 1485682–1485685. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02895k Click here for additional data file. Click here for additional data file.

a. Departamento Química Orgánica, Universidad de Granada (UGR). C. U. Fuentenueva,18071 Granada, Spain. email: [email protected], [email protected] b. Departamento de Fisicoquímica, Facultad de Farmacia, UGR. Cartuja Campus, 18071 Granada, Spain. c. Departamento de Química Orgánica I, Universidad del País Vasco, E-20018, San Sebastián (Spain) d. Departamento de Química, Universidad Autónoma de Mad...